化学气相沉积钨涂层的研究现状与进展

化学气相沉积钨涂层具有工艺简单、技术成熟度高、涂层综合质量优异等特点，广泛应用于国防、航天、核工业等领域。首先介绍了化学气相沉积钨涂层的原理和特点，重点讨论了化学气相沉积钨涂层的工艺及应用研究现状，包括化学气相沉积钨涂层微观组织控制工艺及在耐辐射、耐磨耐蚀和高温防护领域的应用，同时对新型化学气相沉积钨涂层技术的发展进行了展望。一是改善现有工艺存在的反应气源与反应产物毒性大等问题，满足绿色环保的发展要求；二是改善现有工艺存在的沉积温度高、沉积速率偏低等问题，实现在不同衬底表面的高效、高质量沉积；三是改善现有化学气相沉积钨涂层结构与功能单一等问题，满足构件对钨涂层高性能和多功能的需求。     

铅锌多金属矿分段浓缩选别技术的研究与应用

通过多碎细磨、原矿分级溢流优先浓缩脱水,进行了高浓度选铅银、选锌,锌尾矿再浓缩脱水选硫、选锰,同时匹配合理的选矿药剂,原矿浓缩水回用于磨矿分级和选铅,锌尾浓缩水回用于选锌,尾矿浓缩水回用于选硫、选锰,剩余各种废水经适度处理回用于选铅和磨矿分级等,使一段磨矿细度-74μm从70%提高到80%,铅、锌、硫入选初始浓度分别提高到50%、40%、50%,选矿废水全部分质回用。铅锌硫银回收率分别提高了1.5、2.83、13.57、1.01个百分点,硫精矿主品位从38.9%提高到46.5%,设备减少40%、能耗降低25%,节约了选矿药剂消耗和废水处理费用,实现了铅锌多金属矿产资源的高效回收和节能环保。     

煤炭产业环境保护的路径探讨

煤炭在促进经济的同时也给生态环境带来了严重的影响,采取有效措施减少煤炭产业对环境的污染,具有很重要的现实意义。为改善环境污染问题,分析了煤炭产业的环境保护问题并提出相应的解决措施。分析认为,需在国家、地方政府、企业层面强化生态环境保护;从提升资源配置、促进煤炭产业转型升级、加强创新驱动等方面促进资源合理开发;需通过制度保障提升科研协作的成效,促进煤炭绿色开采及清洁利用。在注重环保的同时,落实环境一体化产业政策,向环境依存度较低、知识密集型方向发展,可促进行业可持续发展。     

Weatherability of hybrid organic–inorganic silica protective coatings on glass

Currently, there is a growing interest in the application of silicon-based technologies for the development of advanced hybrid organic–inorganic coatings with strong weatherability. In this study, the sol–gel process is used to prepare such coatings on glass and their resistance to weathering effects is assessed afterwards. Various sols were prepared by mixing a silica-based inorganic matrix (tetraethyl orthosilicate) with different quantities of silica alkoxides functionalised with various organic groups. Subsequently, the sols were dip-coated onto glass samples at low temperatures without any heat treatment. The coatings prepared were analysed before and after three model ageing tests simulating various weathering parameters. After ageing, the best performing coatings showed good overall homogeneity and transparency (optical microscopy, SEM), improved water repellency and adhesion to the glass substrate (static contact angle measurements, cross-cut tape tests) and no colour or chemical composition changes (UV–VIS, FTIR). Compared with commercial hybrid silica products, the alkyl- and methacryloxy-functionalised silica coatings particularly displayed improved homogeneity, elasticity and barrier properties. Thus, these low temperature coatings, easily applicable to thin films, appear to fulfil the main requirements for the protection of the glass exposed to weathering phenomena.     

Graph-based video fingerprinting using double optimal projection

A double optimal projection method that involves projections for intra-cluster and inter-cluster dimensionality reduction are proposed for video fingerprinting. The video is initially set as a graph with frames as its vertices in a high-dimensional space. A similarity measure that can compute the weights of the edges is then proposed. Subsequently, the video frames are partitioned into different clusters based on the graph model. Double optimal projection is used to explore the optimal mapping points in a low-dimensional space to reduce the video dimensions. The statistics and geometrical fingerprints are generated to determine whether a query video is copied from one of the videos in the database. During matching, the video can be roughly matched by utilizing the statistics fingerprint. Further matching is thereafter performed in the corresponding group using geometrical fingerprints. Experimental results show the good performance of the proposed video fingerprinting method in robustness and discrimination.     

瞬态二极管损坏后短路而引起的设备损坏问题探讨

通过在信号防雷器的瞬态二极管前加装一种快速熔断型保险管的方法，使得当瞬态二极管因各种原因损坏至短路后，当短路电流增大至一定程度后，快速熔断型保险管断开从而使瞬态二极管从电路中脱离，保证信号防雷器不会因瞬态二极管短路而引发短路电流，保证后级设备的使用安全。并就瞬态二极管在应用中出现短路损坏时短接电流引起的设备损坏问题提出一种解决方案进行探讨。     

环保新标准的循环流化床锅炉改造分析

对循环流化床在脱硝、脱硫和除尘等方面环保技术路线进行了分析,权衡各项技术的利弊及经济因素,结合新颁布的火电厂大气污染物排放标准(GB 13223—2011),做出如下建议:半干旋转喷雾法脱硫工艺(SDA)和SCR结合使用后,氮氧化物的脱除效率可达到95%,循环流化床中高灰分的环境不适合使用SCR,SNCR的脱除效率虽然相对较低,但是通过调整还原剂的停留时间和与烟气的混合程度,脱硝效率可达70%以上,完全可以满足新环保标准的要求;石灰石-石膏湿法脱硫技术成熟,脱硫效率高,负荷适应性好,在循环流化床炉内脱硫的基础上外加该工艺,可以保证足够的脱硫效率;电袋组合式除尘器发挥了两种除尘器的技术优势,可以达到新标准的要求。     

Improvement of corrosion protective performance of organic coating on low carbon steel by PEO pretreatment

Employing pretreatment is a pressing need for preparing anticorrosive coatings on carbon steels. However, conventional pretreatments are usually based on Cr, P and some other toxic elements, which are harmful to human body. For this reason, green and environmental techniques attract more and more attention. In this paper, plasma electrolytic oxidation (PEO) process was used as a pretreatment to fabricate an underlayer for the organic coating on low carbon steel. The anticorrosive performance of the organic coated samples with and without PEO pretreatment was studied by potentiodynamic polarization, ac/dc/ac electrochemical impedance spectroscopy, salt spray and immersion tests, respectively. Results show that the PEO process produces an oxide layer with porous and rough surface structure on the low carbon steel substrate. The porous and rough PEO layer is beneficial for enhancing the adhesion strength and thickness of the organic topcoatings. The organic coated sample with PEO pretreatment exhibits improved corrosion resistance and longer service life in corrosive environment compared to that without PEO pretreatment.